{"id":10680,"date":"2018-04-17T17:45:30","date_gmt":"2018-04-17T16:45:30","guid":{"rendered":"http:\/\/www.tecnoveritas.net\/?p=10680"},"modified":"2018-10-10T11:05:26","modified_gmt":"2018-10-10T10:05:26","slug":"fuel-desulphurisation","status":"publish","type":"post","link":"https:\/\/www.tecnoveritas.net\/en\/media\/newsletters\/marine-industry\/fuel-desulphurisation\/","title":{"rendered":"Fuel Desulphurisation"},"content":{"rendered":"<div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>Current Context and Challenges<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">We are currently suffering the effects of environmental pollution caused by the emission of pollutants such as carbon dioxide (CO<sub>2<\/sub>), CO, particulate matter (PM), Hydrocarbons (HC), nitrogen oxides (NO<sub>x<\/sub>) and sulfur oxides (SO<sub>x<\/sub>) to the atmosphere. The pollution can have both ashore and maritime origin but generally comes from the incomplete combustion of fuel, the thermal splitting of HC, the high temperature of combustion in the engines cylinder or the oxidation of sulfur (S) in the fuel composition.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Maritime transportation has an impact on the global climate and air quality as well, as a result of the CO<sub>2<\/sub> emissions and other emissions that it generates, such as NO<sub>x<\/sub>, SO<sub>x<\/sub>, methane (CH<sub>4<\/sub>), PM and black carbon (BC). Until a few years ago, shipping remained the only sector of transportation not included in the Union&#8217;s Commitment to reduce Greenhouse Gas Emissions (GHG).<\/p>\n<p><\/div><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>The Sulphur Emissions<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Sulfur in any of its forms reacts with oxygen (spontaneously or upon burning), producing oxides (called SO<sub>x<\/sub>, of which sulfur dioxide (SO<sub>2<\/sub>) is the most known). These sulfur oxides, in the presence of humidity from the combustion processes, turn into acids, such as sulphuric acid (H<sub>2<\/sub>SO<sub>4<\/sub>) and hydrogen sulfide (H<sub>2<\/sub>S) that can originate environmental problems, like acid rain.<\/p>\n<div class='gap nz-clearfix' style='height:0px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Acid rain is harmful to many sectors: agriculture, damaging soils; wildlife, causing deforestation and oceans acidity; damaging monuments; and being extremely harmful to human health, associated to respiratory and cardiovascular diseases, and even cancer.<\/p>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><figure class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10682\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931.jpg\" alt=\"10682\" width=\"2048\" height=\"1536\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931.jpg 2048w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931-300x225.jpg 300w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931-768x576.jpg 768w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931-1024x768.jpg 1024w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/angel-3034931-600x450.jpg 600w\" sizes=\"auto, (max-width: 2048px) 100vw, 2048px\" \/><figcaption class=\"wp-caption-text\">The acid rain effects on monuments.<\/figcaption><\/figure><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><figure class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10683\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848.jpg\" alt=\"10683\" width=\"2816\" height=\"2112\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848.jpg 2816w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848-300x225.jpg 300w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848-768x576.jpg 768w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848-1024x768.jpg 1024w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/dying-tree-557848-600x450.jpg 600w\" sizes=\"auto, (max-width: 2816px) 100vw, 2816px\" \/><figcaption class=\"wp-caption-text\">The acid rain effects on the forest.<\/figcaption><\/figure><\/div><\/div><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">Sulfur is also responsible for the emission of particulates (soot) as the filters used in the means of transportation are rapidly degraded by fuels with a high sulfur content.<\/p>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">In this specific case, MARPOL stipulated limits on sulfur content in Marine Fuel Oil (HFO) as it can be seen in Figure 2. These limits are even more restricted in ECA areas:<\/p>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10701\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01.jpg\" alt=\"10701\" width=\"4413\" height=\"910\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01.jpg 4413w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01-300x62.jpg 300w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01-768x158.jpg 768w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01-1024x211.jpg 1024w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/ECA-Table-01-01-600x124.jpg 600w\" sizes=\"auto, (max-width: 4413px) 100vw, 4413px\" \/><\/div><\/div><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\">When considering other types of fuel for example, US regulations (CCR) defined specific limits on S content in marine gas oils (MGO) and marine diesel oils (MDO).<\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><strong>In Auxiliary Diesel Engines: <\/strong><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Until 30 December 2011, MGO maximum content of 1.5% and MDO a maximum of 0.5%;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>From 1 Jan 2012, MDO with a maximum sulfur content 0.1%.<\/div><\/li><\/ul><div style=\"\" class=\"nz-column-text nz-clearfix\"><strong>In Main Diesel engines and Auxiliary Boilers:<\/strong><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>From 1 July 2009, MGO maximum content of 1.5% and MDO a maximum of 0.5% may be used;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>From 1 Jan 2012, MGO or MDO with a maximum sulfur content 0.1% may be used.<\/div><\/li><\/ul><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><figure class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10703\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01.png\" alt=\"10703\" width=\"1954\" height=\"1415\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01.png 1954w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01-300x217.png 300w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01-768x556.png 768w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01-1024x742.png 1024w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/sulphur-ECA-01-600x434.png 600w\" sizes=\"auto, (max-width: 1954px) 100vw, 1954px\" \/><figcaption class=\"wp-caption-text\">Comparison between the Sulphur limits imposed inside and outside ECA along the different years.<\/figcaption><\/figure><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>Different Techniques to use Low-Sulphur Fuel<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">There are several technologies that can be used in order to prevent the effects of SO<sub>X<\/sub> emissions: <strong>the use of low-sulfur fuel<\/strong>, <strong>the use of Flue Gas Desulphurization (FGD)<\/strong> <strong>techniques<\/strong> or <strong>desulphurization<\/strong> itself.<\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The first option has an economic impact related to their higher costs (low-sulfur heavy fuel has a somewhat higher price than the high-sulfur heavy fuel, due to increasing demand and the cost of the desulphurization process &#8211; Figure 3).<\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><figure class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10708\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/hfo-sulphur.png\" alt=\"10708\" width=\"555\" height=\"349\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/hfo-sulphur.png 555w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/hfo-sulphur-300x189.png 300w\" sizes=\"auto, (max-width: 555px) 100vw, 555px\" \/><figcaption class=\"wp-caption-text\">Comparison of prices on High Sulphur-HFO and Low-Sulphur HFO.<\/figcaption><\/figure><\/div><\/div><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">If it is considered, for example, a ship that processes 4 ton of HFO per hour, it corresponds to a consumption of 35040 tons\/year of HFO. That corresponds to a significant investment representing 15,77 M\u20ac\/year. Another important aspect is the fact that HFO with low-sulfur content has a limited availability. It is foreseen that only HFO with high sulfur levels would be available in a few years period. In that way, ship owners must pay for the fuel high emissions.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Also, there are operative problems considering low-sulfur alternatives to HFO, such as Low Sulphur Distillate Oils (LSDO), since ship owners and manufacturers of marine engines have limited experience using these types of fuel. Furthermore, modifications of the installations are necessary due to the requirement to use such fuels. Regarding operational safety and the ship itself, engines, pumps, boilers and boiler burners should be properly adjusted for the maintenance and burning of LSDO.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">As mentioned above, another interesting technique that can be used to remove SO<sub>x<\/sub> is the Flue-Gas Desulphurization (FGD). It is a set of technologies used to remove sulfur oxides from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes. Though these technologies have several disadvantages:<\/p>\n<p><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>High operating costs;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Increase in power consumption;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Increase in dust emissions;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Cannot be used for waste gas SO2 concentrations greater than 2000 ppm;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Disposal of waste products with significant costs;<\/div><\/li><\/ul><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">An ultimate alternative would be to resort on Desulphurization Techniques. Desulphurization has been commonly used, but many different techniques have been implemented industrially. Among them, the most classic is the Hydrodesulphurization (HDS). This classical process has been implemented in refineries and requires extreme operational conditions: high pressures (30 &#8211; 130 atm), high temperatures (300 &#8211; 400\u00baC) and require a considerable amount of thermal energy. Another risk is the use of hydrogen and the possibility of leakage through the reactor walls. The reaction takes place in a Fixed-Bed reactor, used an expensive solid or metallic catalyst, such as Co\/Mo or Ni\/Mo.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The Hydrodesulphurization (HDS) has some limitations to be pointed out, namely the fact that only enables the conversion of limited sulfur organic compounds present in fuel (Thiols, Thiophenes, Mercaptans, Thioethers, and Disulfides). Relatively to other sulfur compounds like Aromatic and cyclic (Benzothiophenes (BT) or dibenzothiophenes (DBT)) can hardly be removed by this technique.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Another aspect that limits the use of HDS is that it can only be applied for high production capacity factories &#8211; large refineries (requiring high reactors and high reaction times). After HDS other technique has been developed, the Oxidative Desulphurization (ODS). ODS is based on the use of a chemical with high oxidative potential: Hydroperoxide (in most cases H<sub>2<\/sub>O<sub>2<\/sub>-50% V\/V), that will oxidize free and molecular sulfur to its oxide form (Sulphones and Sulphoxides), easier to remove from fuel (substantially more polar than sulfides).<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The oxidant used although it is not a pollutant or harmful to the environment, instead it is expensive and potentially dangerous. This technique allows removing sulfur compounds resistant to HDS, due to the oxidation step. It allows to work with more reasonable operatory conditions (lower temperatures and pressures), don\u2019t require as much thermal energy as HDS, being compatible with smaller processing units in terms of capacity. More recently some studies considered the advantage of combining the oxidant step with the effect promoted by Ultrasounds (Ultrasound &#8211; Assisted Oxidative Desulphurization -UAOD).<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The fundamentals consist in combining the fuel with the oxidizing agent (hydroperoxide) in the presence of an aqueous fluid (for example water), being applied ultrasound to increase the reactivity of the species in the blend. As ODS it enables the users to operate at ambient temperature and atmospheric pressure, to selectively remove sulfur compounds from hydrocarbons. On the other hand, UAOD requires the use of a solid catalyst (Tungstate: CuSO<sub>4<\/sub> or Fe (II)) to regulate the activity of the OH radical. It also requires a phase transfer agent (PTA) to accelerate the conversion of sulfides to sulfones. A final separation step of the technique involves a step of S\/L extraction or L\/L extraction to separate the sulfones from the fuel. UAOD permits to remove sulfur compounds from fuel with a yield of 99,90%.<\/p>\n<p><\/div><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>The fundamentals of DESulphur &#8211; TecnoVeritas\u2019 Disruptive Solution<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">TecnoVeritas has recently developed a Desulphurization technique that can overcome some of the limitations of classical processes consisting in an effective and cleaner way to remove sulfur compounds from sulfur.\u00a0<span style=\"color: #0aa9ff;\"><a class=\"link\" style=\"color: #0aa9ff;\" href=\"https:\/\/www.tecnoveritas.net\/en\/rd-projects\/desulphurisation\/\" target=\"_blank\" rel=\"noopener\"><em>Desulphur<\/em><\/a><\/span> is a patented, new and innovative Desulphurization Process that can be applied to installations (shore and sea) which requires the use of Fuel Oil, Heavy Fuel Oil (HFO), Marine Gas Oil or Marine Diesel Oil.<\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">Due to the restrictive regulation on sulfur content imposed, the lack of fuel with low-sulfur in the market, and to the need of restricting SO<sub>X<\/sub> emissions caused by the oxidation of sulfur in fuel, it was urgent to find the solution. With <strong>Desulphur<\/strong>, users can reduce the sulfur content of their fuels to levels allowed by the regulations at the same time it remains its desirable characteristics (thermal, physical and chemical properties).<\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The process is based in some of the principles and advantages of UAOD but uses a compound with a higher oxidative potential, which is produced on-site and is cleaner (non-pollutant) than hydroperoxides. The produced oxidant promotes a more efficient oxidation of the sulfur compounds present in liquid fuels. The production of the oxidant species combined with the ultrasound system will convert more efficiently the sulfur compounds into oxides and peroxides (due to the increase of reactivity), which are easier to remove.<\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\"><strong>DESulphur<\/strong> is easy to install, requiring no modifications to installations, since it can be installed \u201cIn-Line\u201d. It is also easily adapted to different production capacities and flow rates. It can be implemented on board ships, allowing them to burn fuel with the appropriate sulfur content. The few resultant by-products can be treated as oil waste with onboard systems and dispensed in the usual way.<\/p>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">The process requires the addition of only a few components to the fuel (cheap, easy to obtain and recoverable in the process), and operate at reasonable operation conditions (Low Temperatures and Atmospheric Pressure). The process takes into account the oxidation of sulfur species existing in fuel, to oxides and peroxides that are easier to remove. The oxidation process occurs efficiently due to the presence of an oxidant produced <em>in situ<\/em> and due to the effect of an ultrasound system that creates cavitation and promotes the thermo-ionic dissociation of the water presented in the fuel. A phase separation step allows removing the undesirable components from fuel, obtaining a treated fuel with low-sulfur content.<\/p>\n<p><\/div><\/div><\/div><div class=\"col col6  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><figure class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-10711\" src=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05.png\" alt=\"10711\" width=\"1628\" height=\"978\" srcset=\"https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05.png 1628w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05-300x180.png 300w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05-768x461.png 768w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05-1024x615.png 1024w, https:\/\/www.tecnoveritas.net\/wp-content\/uploads\/2018\/04\/process-05-600x360.png 600w\" sizes=\"auto, (max-width: 1628px) 100vw, 1628px\" \/><figcaption class=\"wp-caption-text\">DESulphur Process Description<\/figcaption><\/figure><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: left;\"><strong>The Advantages<\/strong><\/p>\n<p><\/div><\/div><\/div><div class=\"col col4  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: center;\"><b>Economic<\/b><\/p>\n<p><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>The oxidant agent is produced in situ, therefore there is no need to add external compounds to the process;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>The process doesn\u2019t require significant amounts of energy, presenting low operation\/processing costs;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>All reagents used are not expensive and are relatively easy to obtain. These reagents can be recovered in the process with high yields;<\/div><\/li><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>DESulphur uses relatively low temperatures and pressures (which involve lower costs), comparing to HDS, for example.<\/div><\/li><\/ul><\/div><\/div><div class=\"col col4  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: center;\"><strong>Security<\/strong><\/p>\n<p><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>The process doesn\u2019t present any safety hazard in terms of storage and handling, and all operative conditions are reasonable. <\/div><\/li><\/ul><\/div><\/div><div class=\"col col4  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" ><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: center;\"><strong>Environmental<\/strong><\/p>\n<p><\/div><ul class=\"nz-i-list none\"><li><div><span class=\"icon icon-arrow-right8\" style=\"color:#636363;\"><\/span><\/div><div>Process compatible with low flow rates, it can be implemented on board ships allowing them to burn fuel with the appropriate content of sulphur. By-products can be treated as oil residues by dedicated on-board systems and dispensed in the usual way.<\/div><\/li><\/ul><\/div><\/div><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\">The TecnoVeritas Desulphurisation technique is disruptive compared to the other classic techniques, due to the fact it uses a higher oxidative potential agent produced <em>in-situ<\/em> and cleaner. The produced oxidant guarantees in combination with the ultrasound effect a more efficient oxidation of the Sulphur species, allowing an easier removal.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">The purified fuel (with lower sulfur content) maintains its desirable properties and can be used for maritime applications, but it is not limited to it.<\/p>\n<p><\/div><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"padding-bottom:30px;\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>Market and Applications<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">It can be used on a global scale (within maritime and industrial sectors), with a special interest in countries with seaports delivering greater economic, energy, operational\/safety and environmental advantages. An example of sectors in which it could be used is petroleum industry, waste treatment and recovery of fuels, fuel producers, global industries that use heavy fuel in their activities or naval sector.<\/p>\n<p><\/div><\/div><\/div><\/div><\/div><div  class=\"nz-section horizontal animate-false full-width-false\"   data-animation-speed=\"35000\" data-parallax=\"false\" style=\"\"><div class=\"nz-row\"><div class=\"col col12  col-animate-false\" data-align=\"left\" data-effect=\"fade-left\" data-margin=\"false\"><div class=\"col-inner\" style=\"\"><div style=\"\" class=\"nz-column-text nz-clearfix\"><\/p>\n<p style=\"text-align: justify;\"><strong>Conclusions<\/strong><\/p>\n<p style=\"text-align: justify;\"><div class='gap nz-clearfix' style='height:15px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">A brief economical evolution of the process was made to establish its viability. For instance, consider an installation that processes 4 tons of fuel per hour, the estimated investment is calculated to be recovered in about 9 months. The calculations were made taking into account the current fuel prices, assuming a unit utilization factor of 80%, and including the maintenance cost of the desulphurization plant.<\/p>\n<div class='gap nz-clearfix' style='height:10px'>&nbsp;<\/div>\n<p style=\"text-align: justify;\">TecnoVeritas developed a revolutionary product that could be the solution to solve a global problem of harmful emissions to the environment. It can offer numerous advantages compared to conventional desulphurization techniques. Its applications can be applied to a worldwide level, considering the diversity of customers that can go from industrial to the maritime sector.<\/p>\n<p><\/div><\/div><\/div><\/div><\/div>","protected":false},"excerpt":{"rendered":"Current Context and Challenges &nbsp; We are currently suffering the effects of environmental pollution caused by the emission of pollutants such as carbon dioxide (CO2), CO, particulate matter (PM), Hydrocarbons (HC), nitrogen oxides (NOx) and sulfur oxides (SOx) to the atmosphere. 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